The label and cover art reference copyright 1994 but I couldn't come up with any other information about this release being previously released. Not in this format anyway.
This is a really nice compilation of demos, rehearsal takes, one-off appearances, etc. The overall sound quality is superb and evenly mastered, given the various caliber of the recordings themselves. The tracks are presented with a very thoughtful flow which makes for an enjoyable listening experience, which is nice when the label could have easily taken the chronological approach. Highly recommended for the Nirvana completists.